山东省聊城第四中学;
以2,4,5-三氟-3-甲氧基苯甲酸、1,10-邻菲罗啉和醋酸铜为配体原料,以甲醇做溶剂,常温条件下反应2h,得到了一个单核五配位的金属铜羧酸配合物,通过元素分析、红外光谱及X-射线单晶衍射技术对该配合物进行了充分表征,并通过理论计算,研究了标题化合物的前线轨道理论.而且,由于活性基团氟原子、氧原子以及大的共轭体系邻菲罗啉的存在,分子间还存在C-H...F、C-H...O氢键,以及苯环和苯环之间的π-π堆积作用,这些作用将分子连接成了一个稳定的二维网状结构.
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| 下载次数 | 被引频次 | 阅读次数 |
[1]孟跃,陈蕊,赵叶民,倪生良.双核钴配合物[Co2(phen)4(C8H7O2)2](Cl O4)2·2Et OH的合成与结构[J].化学试剂,2013,35(9):837-840.
[2]毕建洪,熊付超,张悠金.对苯二甲酸根桥联双核铜(II)配合物的合成[J].商丘师范学院学报,2005,21(5):93-95.
[3]席玉蕾,叶庆国.三氟乙酸铜与邻菲罗啉配合物的合成[J].青岛科技大学学报(自然科学版),2011,32(6):576-579.
[4]储召华,解庆范,陈延民.一维链状锌聚合物{[Zn(H2O)2(L)(phen)]·3H2O}n的合成、晶体结构和性能研究[J].无机化学学报,2013,29(9):1893-1896.
[5]C.L.Ma,J.S.Sun,R.F.Zhang,D.Q.Wang.Self-assembled diorganotin(IV)moieties with 2,3,4,5-tetrauorobenzoic acid:Syntheses,characterizations and crystal structures[J].Inorg.Chim.Acta.,2006(359):4179-4190.
[6]C.L.Ma,J.S.Sun,R.F.Zhang.Self-assembly of triorganotin(IV)moieties with 4,4'-bipy,triphenylphosphine oxide 2,3,4,5-tetrauorobenzoic acid and 4,4'-bipy,phen:Syntheses,characterizations and supramolecular structures[J].J.Organomet.Chem.,2006(691):5885-5898.
[7]C.L.Ma,J.S.Sun,R.F.Zhang.Trinuclear organooxotin assemblies from solvothermal synthesis reaction:Crystal structure,hydrogen bonding and stacking interaction[J].J.Mol.Struct.,2007(833):203-207.
[8]M.Gielen,A.El Khlou,M.Biesemans,R.Willem.Di-n-butyltin and diethyltin monofluorobenzoates:Synthesis,spectroscopic characterization and in vitro antitumor activity[J].Appl.Organomet.Chem.,1993(7):119-125.
[9]M.Gielen,M.Biesemans,A.El.Khlou,et al.Diorganotin difluorobenzoates:synthesis,spectroscopic characterization and in vitro antitumour activity X-Ray structure determination of bis[di-n-butyl(2,6-difluorobenzoato)tin]oxide[J].J.Fluorine.Chem.,1993(64):279-291.
[10]M.Gielen,A.El Khlou,D.de Vos,et al.Bis[di-n-butyl(tri-and tetrafluorobenzoato)]tin oxides:synthesis,characterization and in vitro antitumour activity Bull[J].Soc.Chim.Belg.,1993(102):761-764.
[11]M.Gielen,A.El Khlou,M.Biesemans,et al,Diorganotin 2-fluorocinnamates and 4-fluorophenylacetates:Synthesis,characterization and in vitro antitumour activity[J].Appl.Organomet.Chem.,1993(7):201-206.
[12]M.Gielen,M.Boualam,A.Meriem,et al.Dialkyltin derivatives of dicarboxylic acids:Synthesis,characterization and in vitro antitumor properties[J].Heteroatom.Chem.,1992(3):449-452.
[13]A.Bondi.Van der waals volumes and radii[J].J.Phys.Chem.,1964(68):441-451.
基本信息:
DOI：
中图分类号:O641.4
引用信息:
[1]夏丽丽.含氟羧酸铜(Ⅱ)配合物[Cu(phen)(CH_3OF_3C_6HCOO)_3]的合成、晶体结构及理论研究[J].泰山学院学报,2016,38(06):85-89.
基金信息: